ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

pH-controlled new mixed-ligand coordination polymers: luminescent properties and promotion activity on the children bone growth and development

Ping Jiang, Xiao-Qing Liu, Ai-Ling Sun, Cong Wang, and De-Guang Liu

Department of Pediatrics, Shandong Sunshine Union Hospital, Weifang, China

E-mail: Liudeguang2021@163.com

Received: 24 May 2021  Accepted: 17 July 2021

Abstract:

Through precisely adjusting the pH value of reaction system, two new mixed-ligand based coordination polymers, namely [Zn(ip)_0.5(bta)]_n (1) and [Zn₃(Hip)₄(bta)₂]_n (2) (H₂ip = isophthalic acid, Hbta = benzotriazole), have been acquired through the self-assemble reaction of Zn(II) salts in combination with H₂ip and Hbta. Both compounds have high thermal stability demonstrated by the thermogravimetric analysis (TGA) experiments, and exhibit strong luminescence emission at room temperature. Their application values on the children bone growth and development were evaluated and the specific mechanism was examined simultaneously. Above all, compound 1 was more outstanding than compound 2 against the children bone growth and development by regulating the Vitamin K receptor on the bone cell surface.

Graphic abstract

Keywords: Zn(II) compound; Luminescence; Bone growth and development

Full paper is available at www.springerlink.com.

DOI: 10.1007/s11696-021-01798-2

Chemical Papers 75 (12) 6345–6353 (2021)