ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Synthesis, characterisation and corrosion inhibition screening on 2-chloroacetophenone 4-ethyl-3-thiosemicarbazone: morphology, weight loss and DFT studies

Nur Zalin Khaleda Razali, Sheikh Ahmad Izaddin Sheikh Mohd Ghazali, Idris Sharif, Suhaila Sapari, Fazira Ilyana Abdul Razak, and Nur Nadia Dzulkifli

School of Chemistry and Environment, Faculty of Applied Sciences, Universiti Teknologi MARA Cawangan Negeri Sembilan, Pekan Parit Tinggi, Kuala Pilah, Malaysia

E-mail: nurnadia@uitm.edu.my

Received: 18 April 2022  Accepted: 21 May 2022

Abstract:

Mild steel is often used as a construction material in the industry because of its relatively low price. However, due to its low corrosion resistance, some form of a protective film should be applied to prevent it from rusting in the corrosive environment. Thiosemicarbazone is one of the Schiff base ligands that can inhibit corrosion due to the presence of electronegative atoms such as N, S, and π electrons that can cause an efficient adsorption on the mild steel surface. This research aims to synthesise of 2-chloroacetophenone 4-ethyl-3-thiosemicarbazone (2ClAcTSC) and the structure was confirmed using an elemental analyser, UV–Vis, NMR and ATR-FTIR. The inhibitive effects of 2ClAcTSC were studied on mild steel in 1 M HCl and H₂SO₄ by using the weight loss method and Scanning Electron Microscopy (SEM). It was found that the 2ClAcTSC has better effectiveness in HCl rather than H₂SO₄ solution. Moreover, the inhibition efficiency increases as the inhibitor concentration increases. The SEM results verified that the inhibitor had been adsorbed on the mild steel surface to form a protective layer. Density Functional Theory (DFT) computations are performed to correlate inhibitor efficiency with intrinsic molecular parameters. The study revealed that the results obtained are consistent with the experimental data reported.

Keywords: Thiosemicarbazone; Corrosion; Acid; Weight loss; Density Functional Theory

Full paper is available at www.springerlink.com.

DOI: 10.1007/s11696-022-02297-8

Chemical Papers 76 (9) 5955–5966 (2022)