ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Environmental microplastics and their additives—a critical review on advanced oxidative techniques for their removal

Kingsley I. John, Martins O. Omorogie, Ajibola A. Bayode, Aderemi T. Adeleye, and Brigitte Helmreich

College of Science, Health, Engineering and Education, Murdoch University, Murdoch, Australia

E-mail: omorogiem@run.edu.ng

Received: 9 April 2022  Accepted: 19 September 2022

Abstract:

Microplastics (MPs) and their additives are a major concern to the environment and public health due to their toxicity. MPs originate from different categories of plastics, namely polyethylene (PE), polystyrene (PS), polyvinyl chloride (PVC), and polyethylene terephthalate (PET). The removal of MPs and their additives including bisphenol A (BPA), nonylphenol (NP), and tetrabromobisphenol A (TBBPA) has been a major challenge. Recently, advanced oxidation processes (AOPs) have been demonstrated to be more effective for the removal of MPs and their additives than traditional methods. Meanwhile, there are still limited studies on the application AOPs for their remediation. Consequently, there is a need for more investigation on the remediation of MPs and their additives. This review investigates the degradation of common MPs (PE, PS, PVC, and PET) and their additives (NP, BPA, and TBBPA) using AOPs including photocatalysis (PC), (electrocatalysis) photoelectrocatalysis (PEC), electro-Fenton (EF), and sonocatalysis. In-depth analyses reveal reactive oxygen species (ROS) as a driving force for the efficiency of AOPs. The complete removal of environmental MPs and their additives is quite promising with the AOPs.

Graphical abstract

Keywords: Microorganisms; Plastics; Photocatalysis; Fenton; Electrocatalysis; Pollution

Full paper is available at www.springerlink.com.

DOI: 10.1007/s11696-022-02505-5

Chemical Papers 77 (2) 657–676 (2023)