ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

(E)-Cinnamoylferrocene 5-Benzylcarbodithioylhydrazone and its Chelates

Guo-Sheng Huang, Yong-Hong Liu, Bao-Hua Chen, and Yong-Xiang Ma

Department of Chemistry, Lanzhou University, Lanzhou 730000, China

Abstract: A new organometallic compound, (E)-cinnamoylferrocene S-benzylcarbodithioylhydrazone (HCfbc) and its chelates with some metal(II) acetates, M(Cfbc)₂.nH₂O (M = Co²⁺, Ni²+, Cu²+, Zn²⁺, Cd²⁺, and Hg²⁺; n = 0-1) were prepared aad characterized by elemental analysis, IR, ¹H NMR, and molar conductance. It is shown that HCfbc appears to be a bidentate ligand with trans configuration and to coordinate the metal through the azomethine nitrogen and thioenolic sulfur atom.

Full paper in Portable Document Format: 531a65.pdf

Chemical Papers 53 (1) 65–68 (1999)