ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Synthesis and Properties of Tripropylammonium Decavanadates

Ľ. Žúrková, Š. Špaček, and I. Tkáč

Department of Inorganic Chemistry, Faculty of Natural Sciences, Comenius University, SK-842 15 Bratislava

Abstract: [TPAH]₄H₂V₁₀O₂₈. nH₂O (A) and [TPAH]₃H₃V₁₀O₂₈ (B) were prepared by dissolving of V₂O₅ in an aqueous solution of tripropylamine (TPA). The IR spectra of the hydrogendecavanadates prepared exhibit small differences in their metal-oxygen framework structures. In course of the thermal decomposition of A the anhydrous [TPAH]₄H₂V₁₀O₂₈ was formed at 100°C.

Full paper in Portable Document Format: 485a295.pdf

Chemical Papers 48 (5) 295–299 (1994)