ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Preparation of Some 2,6-Anhydroheptoses via  Ozonolysis of Sodium 2,6-Anhydro-1-deoxyheptitol-1- nitronates

M. Petrušová, I. Stručková, M. Matulová, and L. Petruš

Institute of Chemistry, Slovak Academy of Sciences, CS-842 38 Bratislava

Abstract: Ozonolysis of 2,6-anhydro-7-deoxy-7-nitro-L-glycero-L-galacto-heptitol*, 2,6-anhydro-1-deoxy-1-nitro-D-glycero-D-gulo-heptitol, and 2,6-anhydro-1-deoxy-1-nitro-D-glycero-D-galacto-heptitol, respectively, in aqueous sodium hydroxide at room temperature gave rise to the corresponding 2,6-anhydroheptoses. The products of the conversion were isolated as 2,4-dinitrophenylhydrazones and were characterized by ¹H and ¹³C  NMR spectroscopy.

Full paper in Portable Document Format: 473a195.pdf

Chemical Papers 47 (3) 195–197 (1993)