ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Nitrofuran derivatives of cellulose. 10. 5-nitrofurfurylidene derivatives of 2,4-dihydrazino-6-oxy-celluloso-s-triazine and of 2,3-dihydrazinocellulose

P. Krkoška, L. Potančok, L. Dubecký, and A. Blažej

Department of Textile, Pulp, and Paper, Slovak Technical University, CS-81237 Bratislava

Abstract: Reduction of 2,3-dicarbonylcellulose hydrazone gives rise to 2,3-deoxydihydrazinocellulose. Reaction of 2,4,6-trichloro-s-triazine with cellu­lose enables one to prepare 2,4-dichloro-6-oxycelluloso-s-triazine followed by 2,4-dihydrazino-6-oxycelluloso-j-triazine and after that by (2,4-dihydrazino-6-s-triazino)-2,3-dicarbonylcellulose, (2,4-dihydrazino-6-s-triazino)-2,3-dihydrazonocellulose and (2,4-dihydrazino-6-s-triazino)-2,3-deoxydihydrazinocellulose, respectively. The dihydrazino derivatives give through condensation with 5-nitro-2-furaldehyde the appropriate 5-nitrofurfurylidene derivatives. The behaviour of some of the selected materials being under thermogravimetric conditions is presented.

Full paper in Portable Document Format: 414a511.pdf

Chemical Papers 41 (4) 511–518 (1987)