ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7

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Adsorption of metal-ions on dehydrochlorinated polyvinyl-chloride)

P. Šimon, L. Valko, and D. Kolkusová

Department of Physical Chemistry, Slovak Technical University, CS-812 37 Bratislava

 

Abstract: The adsorption of metal ions from their aqueous solutions on dehydrochlori- nated poly(vinyl chloride) has been experimentally studied and tested by Langmuir's isotherm. It has been found that the amount of Hg(II) adsorbed increases with increasing temperature and the adsorption enthalpy of the process is -17 kJ mol-1. Adsorption on dehydrochlorinated PVC has been observed also in the case of Ag(I), Pb(II), and Fe(II). Ni(II), Zn(II), Pd(II), Ca(II), and Cu(II) exhibit no adsorption.

Full paper in Portable Document Format: 404a513.pdf

 

Chemical Papers 40 (4) 513–517 (1986)

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