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ISSN electronic edition: 1336-9075
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Complex-compounds of nickel with salicylaldoxime

F. Bŕezina, H. Tillmannová, and Z. Šindelář

Department of Inorganic and Physical Chemistry, Faculty of Natural Sciences, Palacký University, CS-771 47 Olomouc

 

Abstract: Some octahedral complexes of the Ni(HSal)2 • LL- nH20 type (LL = 1,10-phenanthroline,  α,α'-bipyridyl or ethylenediamine and n =0.1) were prepared by using the reaction of Ni(HSal)2 (H2Sal = salicylaldoxime— C7H7NO2) with bidentate ligands. The reaction of Ni(HSal)2 with bromine results in bromination of the aromatic ring of ligand. The possibility of oxidizing Ni(HSal)2 with peroxodisulfaté or hydrogen peroxide has been studied.

Full paper in Portable Document Format: 406a727.pdf

 

Chemical Papers 40 (6) 727–733 (1986)

Tuesday, June 25, 2024

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