ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Composition of the fluorooxoperoxo complexes of vanadium(v) crystallizing from acid-medium

P. Schwendt, D. Joniaková, and V. Ezr

Department of Inorganic Chemistry, Faculty of Natural Sciences, Komenský University, CS-842 15 Bratislav

Abstract: Some problems involved in the determination of composition of the fluoro- oxoperoxo complexes of vanadium(V) obtained from acid medium are discus- sed in this paper. Owing to low stability of these complexes, the prepared substances may contain decomposition products, which results in a decrease in content of the peroxidic oxygen and formulation of the obtained substances as complexes with the ratio n(Ol~)/n(V) = 1. The existence of the fluorooxopero- xo complexes of this type has not been hitherto confirmed.

Full paper in Portable Document Format: 393a353.pdf

Chemical Papers 39 (3) 353–360 (1985)