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Electrochemical resolution of cyanide-linkage isomers in the course of the reaction of [Cr(CN)2(H2O)3NO] with  Hg2+ ions

M. Rievaj and D. Bustin

Department of Analytical Chemistry, Slovak Technical University, CS-812 37 Bratislava

 

Abstract: Transformation by semi-differentiation was employed to raise the resolving power off voltammetry with a stationary hanging Hg drop electrode. This technique was applied to analyze components with small differences in halfwave potentials by using the method of subtraction of the peak of 1 component from curve of coinciding peaks for the anal. of intermediates and products of multistep reaction of [Cr(CN)2(H2O)3NO] with Hg2+.

Full paper in Portable Document Format: 386a749.pdf

 

Chemical Papers 38 (6) 749–757 (1984)

Wednesday, September 28, 2022

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