ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Realization and properties of a silver diethyldithiocarbamate electrode

J. Labuda, J. Mocák, and M. Skatuloková

Department of Analytical Chemistry, Slovak Technical University, CS-812 37 Bratislava

Abstract: Metal-complex electrode was studied of the aq. Ag(I) diethyldithiocarbamate-diethyldithiocarbamate anion type. Formal potential values were assessed and the slope of graphic dependence of potential on the logarithm of relative concn. was detd. for the Ag and Ag-diethyldithiocarbamate electrodes, resp., in DMSO, MeOH as well as in H₂O (ionic strength of NaClO₄ soln. being 0.1 mol dm^-3). Ag(Et₂dtc) complexing is obsd. Values of its stability const. in the stated media as well as the value of its soly. product in water are given.

Full paper in Portable Document Format: 381a59.pdf

Chemical Papers 38 (1) 59–66 (1984)