ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Thermodynamic proof of the existence of compounds in the phase diagrams of systems without solid solutions. I. Description of the method and its testing on a model system

M. Malinovský and J. Vrbenská

Department of Inorganic Technology, Slovak Technical University, 880 37 Bratislava

Abstract: Thermodynamic analysis of the course of liquidus curve of substance A in the system A—В makes it in principle possible to determine the existence of a complex compound which occurs in this system. К the behaviour of the system is not very far from ideality, the stoichiometric coefficients of the compound and the degree of its thermal dissociation can be calculated as well.

Full paper in Portable Document Format: 356a737.pdf

Chemical Papers 35 (6) 737–745 (1981)