ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Preparation and characterization of magnesium oxide-bound trichlorobis(tetrahydrofuran)titanium(III)

G. Plesch, E. A. Paukshtis, E. S. Sanko, S. Rapiová, E. N Yurchenko, and M. Zikmund

Institute of Inorganic Chemistry, Slovak Academy of Sciences, 809 34 Bratislava

Abstract: The anchoring of the coordinatively unsatd. complex TiCl₃(C₄H₈O)₂ to the surface of MgO leads to the formation of surface attached Ti(III) complexes, which were investigated by ESR and IR spectroscopy. The anchoring of the original complex to the surface is achieved by the reaction of the complex with the basic centers on the surface of MgO. On thermal decompn. of thus formed surface complexes their aggregation takes place. By their reaction with mol. O the radical O₂^- arises which is coordinated to Ti(IV).

Full paper in Portable Document Format: 355a613.pdf

Chemical Papers 35 (5) 613–619 (1981)