ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Thermal decomposition of potassium μ-oxo- and μ-hydroxo-bis(oxodiperoxovanadate)

P. Schwendt and D. Úškert

Department of Inorganic Chemistry, Faculty of Natural Sciences, Komenský University, 816 31 Bratislava

Abstract: In the systematic study of slow decompn. of V(V) peroxo compds., the products of thermal reactions of K₄[V₂O₃(O₂)₄].2H₂O and K₃[HV₂O₃(O₂)₄].H₂O were studied under conditions which did not allow a rapid liberation of peroxidic O. The decompn. intermediates react with CO₂ present in air and the final products of decompn. of both compds. are KVO₃ and K₃[VO(O₂)₂(CO₃)].

Full paper in Portable Document Format: 352a229.pdf

Chemical Papers 35 (2) 229–233 (1981)