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Reactions of saccharides catalyzed by molybdate ions. XXX. Epimerization of D-[U-14C]glucuronic acid

V. Bílik, R. Sandtnerová, Z. Krátky, and L. Petruš

Institute of Chemistry, Slovak Academy of Sciences, 809 33 Bratislava

 

Abstract: Epimerization of D-[U-14C]glucuronic acid catalyzed by molybdate ions offers an equil. mixt. of D-[U-14C]glucuronic and D-[U-14C]mannuronic acid in the ratio 5:1 and small amts. of D-[U-14C]lyxo-5-hexulosonic acid. D-[U-14C]Glucuronic acid was obtained on hydrolysis of α-[U-14C]glucan oxidized by NO2.

Full paper in Portable Document Format: 344a518.pdf

 

Chemical Papers 34 (4) 518–523 (1980)

Wednesday, September 28, 2022

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