ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7
Cyanatocopper(II) complexes with organic ligands. XVII. Preparation and physical properties of cyanatocopper(II) complexes with aliphatic and related amines
J. Kohout, A. Mašlejová, and J. Gažo
Department of Inorganic Chemistry\ Slovak Technical University,
880 37 Bratislava
Abstract: The cyanatocopper(II) complexes of the type Cu(NCO)2L2, where L=allylamine, propylamine, butylamine, benzylamine, cyclohexylamine, and
diethylamine were prepared and studied using infrared, electronic, and e.s.r.
spectroscopy and room temperature magnetic moments. From the results of
these measurements it follows that the Cu(II) atom in the studied complexes
has tetragonal stereochemistry from pseudooctahedral to practically planar.
Degree of the axial interaction is influenced by basicity of the ligand L as well
as by its steric and crystallostructural effects.
Full paper in Portable Document Format: 343a320.pdf
Chemical Papers 34 (3) 320–329 (1980)
Wednesday, November 29, 2023