ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Molar electrical conductivity of the system  Ca(NO₃)₂ + CaBr₂ + H₂O

J. Novák and I. Sláma

Institute of Inorganic Chemistry, Czechoslovak Academy of Sciences, 160 00 Prague

Abstract: Molar elec. cond. λ of the system Ca(NO₃)₂ + CaBr₂ + H₂O was studied as a function of temp. and compn. The ratio between ions NO3- and Br- was expressed as anionic fraction y (y = [Br^-]/([Br^-] + [NO₃^-])) and it assumed values 0.1, 0.2, 0.3, 0.4, and 1.0. Mole fraction of calcium salts (calcd. on the basis of sum of moles of anhyd. calcium salts and moles of water) ranged from 0.06 to 0.125. The dependence of molar elec. cond. λ on anionic fraction y (in the range 0.0-0.4 at const. temp. and total concn. of salts in the system) was described using the modified Markov-Shumina (1956) equation.

Full paper in Portable Document Format: 343a341.pdf

Chemical Papers 34 (3) 341–347 (1980)