ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Photosensitized oxidation of iron(II) to iron(III) in systems of iron chloro complexes in nonaqueous medium

J. Šima, H. Zliechovcová, and J. Gažo

Department of Inorganic Chemistry, Slovak Technical University, 880 37 Bratislava

Abstract:  Results of the study of the oxidation of Fe(II) to Fe(III) photosensitized by the Fe (III) complexes or tetracene in electronic-excited states are presented in this paper. The course of this oxidation was investigated with the systems of Fe(II) and Fe(III) chloro complexes in acetone—methanol mixtures. The values of constants of the Stern—Volmer equation are given and the mechanism of photoprocesses in these systems is discussed.

Full paper in Portable Document Format: 342a172.pdf

Chemical Papers 34 (2) 172–178 (1980)