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Influence of hydrogen bonds on acid-base properties and polarographic reduction of amide oximes

J. Mollin, F. Grambal, F. Kašpárek, T. Kučerová, J. Lasovský, and N.T.Son

Department of Inorganic and Physical Chemistry, Faculty of Natural Sciences, Palacký University, 771 46 Olomouc


Abstract: The presence of H bonding between amide oximes and solvent was studied by IR. On the basis of solvation of the functional groups, the changes in pK and half-wave potentials of the polarog. redn. due to substitution were explained. The dependence of pK on the reciprocal value of relative permittivity of solvent was investigated. A good correlation between pK and 1H NMR spectra of the substances was obsd.

Full paper in Portable Document Format: 334a458.pdf


Chemical Papers 33 (4) 458–466 (1979)

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