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ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7
Published monthly
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Reaction of distortion isomers of dithiocyanatobis(pyridine)copper(II) with pyridine
M. Kabešová, B. Papanková, and J. Gažo
Department of Inorganic Chemistry, Slovak Technical University,
880 37 Bratislava
Abstract: Reactions of α- and ß-Cu(py)2(NCS)2 with pyridine are described. The conditions are
specified under which a pair of modifications of Cu(py)4(NCS)2 complex is prepared by
reactions of α- and ß-Cu(py)2(NCS)2 with pyridine as well as the conditions under which
these reactions give rise to products with composition Cu(py)4(NCS)2 having the same
physicochemical properties. The properties of prepared compounds were studied by
thermal methods. Some properties of intermediate products of thermal decomposition of
α- and ß-Cu(py)4(NCS)2 are also described. The differences between properties of
prepared modifications suggest the presence of fine structural differences analogous to
those observed for α- and ß-Cu(py)2(NCS)2.
Full paper in Portable Document Format: 301a35.pdf
Chemical Papers 30 (1) 35–41 (1976)
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