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Thermal analysis of cesium zinc vanadates

Ľ. Ulická

Department of inorganic Chemistry, Faculty of Natural Science., Komenský University) 801 00 Bratislava

 

Abstract: The thermal decompn. of Cs2Zn(VO3)4.2.5H2O (I) and Cs2Zn2V10O28.14H2O (II) were studied. The products were characterized by x-ray phase anal. and IR spectroscopy. Some structural changes and partial redn. of V(V) took place after dehydration of I. Redn. was also obsd. with II, which decompd. at higher temps. to give a mixt. of Cs2V6O16 and Zn(VO3)2.

Full paper in Portable Document Format: 304a416.pdf

 

Chemical Papers 30 (4) 416–424 (1976)

Wednesday, May 22, 2024

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