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Classification of Temkin's ideal ionic solutions

M. Malinovsk√Ĺ

Department of Inorganic Technology, Slovak Technical University, 88037 Bratislava

 

Abstract: Classification of M. Temkin's (1945) ideal ionic solns. from the point of view of Raoult's and Henry's laws is presented. In binary solns., these laws are obeyed for both components only if these components have common ions and if the stoichiometric coeff. of the non-common ion equals one. In the case of components having common ions where the condition of unit stoichiometric coeffs. at non-common ion is not fulfilled as well as in the case of components with non-common ions, none of these laws is valid. The exceptional behavior of solns. formed by components MAq + NrAt is analyzed.

Full paper in Portable Document Format: 306a730.pdf

 

Chemical Papers 30 (6) 730–736 (1976)

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