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Hydrogen bonding in phenols. X. The nuclear magnetic resonance data of hydrogen bonds of 2-hydroxydiphenylmethane, 2-hydroxydiphenyl ether, sulfide, and selenide

A. Kanala, E. Solčániová, and Š. Kováč

Department of Organic Chemistry, Slovak Technical University, 880 37 Bratislava

 

Abstract:  On the basis of temperature measurements intramolecular and intermolecular hydrogen bonds of 2-hydroxydiphenylmethane, 2-hydroxydiphenyl ether, sulfide, and selenide in CDCI3 solution have been studied. o-Cresol, guaiacol, 2-hydroxythioanisole, and 2-hydroxy>selenoanisole have been used as model compounds. From the temperature dependence of the chemical shifts of OH protons a possibility to resolve various types of hydrogen bonds in the compounds studied has been discussed.

Full paper in Portable Document Format: 293a392.pdf

 

Chemical Papers 29 (3) 392–396 (1975)

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