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Thermogravimetric investigation of some chloro(pyridine) complexes of titanium(III)

M. Zikmund, A. Valent, and K. Hrnčiarová

Institute of Inorganic Chemistry, Slovak Academy of Sciences, 809 34 Bratislava

 

Abstract:  The thermogravimetric studjr of the compounds of the composition TiCl3Ln (where L is pyridine and its alkyl derivatives, and n = 1 — 3) showed the intermediate formation of pale yellow complex ТiClз(ру)2. Each of the compounds decomposed, ultimately, to the solid black titanium(II) chloride and to volatile yellow aclduct TiCI4L2.

Full paper in Portable Document Format: 295a606.pdf

 

Chemical Papers 29 (5) 606–611 (1975)

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