ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Reactions of cumyloxy radicals in n-heptane at 50°C

R. Rado, I. Chodák, and V. Ďurďovič

Polymer Institute, Slovak Academy of Sciences, 809 34 Bratislava

Abstract:  On the basis of the obtained data about decomposition products of cumyl hydroperoxide catalyzed by cobalt(II) cations in n-heptane at 50°C, the mechanism of the formation and the decay of cumyloxy radicals in saturated hydrocarbon are discussed and the value of their relative transfer reactivity is derived.

Full paper in Portable Document Format: 281a64.pdf

Chemical Papers 28 (1) 64–69 (1974)