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Conformation of 1,2-isopropylidene derivatives of α-D-glucopyranose

C. Peciar, J. Alföldi, R. Palovčík, and P. Kováč

Institute of Chemistry, Slovak Academy of Sciences, 809 33 Bratislava

 

Abstract:  The conformation of l,2-0-isopropylidene-3,4,6-tri-O-methyl-a-D-glucopyranose and l,2-0-isopropylidene-4,6-di-0-methyl-α-D-glucopyranose in solution were investigated by p.m.r. spectroscopy. The above-mentioned substances adopt essentially the skew-boat conformation under the given conditions of measurement.

Full paper in Portable Document Format: 271a90.pdf

 

Chemical Papers 27 (1) 90–93 (1973)

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