ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Physico-Chemical Properties of the System Na₃AlF₆—NaCl—Ti0₂

T. P. Madhavan, K. Matiašovský, and V. Daněk

Institute of Inorganic Chemistry, Slovak Academy of Sciences, Bratislava 9

Abstract: The phase equilibria, density and specific electrical conductivity in the system Na₃AlF₆ —NaCl—Ti0₂ were studied. The phase diagram, the density and the electrical conductivity isotherms at 1050°C are presented. On addition of Ti0₂ , a decrease in the values of density and conductivity was observed. An attempt was made to calculate the liquidus curve and to compare it with the experimentally determined curve for the system Na₃AlF₆ —NaCl. The molar volumes of the binary Na₃AlF₆ —NaCl mixtures, as well as partial molar volumes and the excess molar volumes were calculated from the density data.

Full paper in Portable Document Format: 254a253.pdf

Chemical Papers 25 (4) 253–258 (1971)