ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Radioactive Kryptonates in Volumetric Analysis (I) Radioactive Kryptonates — New Chelatometric Indicators

J. Tölgyessy, Š. Varga, V. Jesenák, and D. Hroncová

Department of Radiochemistry and Radiation Chemistry, Slovak Technical University, Bratislava

Abstract: A method employing radioactive kryptonates as the end point indicators in chelatometric titrns. was described. The end point is detd. with the solid radioactive kryptonate AB[⁸⁵Kr], added to the soln. before the beginning of the titrn. After the end point is exceeded, the excess of the added chelate-forming agent reacts with the radioactive kryptonate liberating radioactive ⁸⁵Kr.  Principles of the titration method, methods for preparing radioactive kryptonated indicators, experimental results of kryptonation and a study of the properties of prepared radioactive kryptonates from the point of view of their application as indicators in radiochelatometrie titrations are given in this paper.

Full paper in Portable Document Format: 221a3.pdf

Chemical Papers 22 (1) 3–14 (1968)