ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Aminolysis of sucrose. IV. Reaction of sucrose with aqueous solution of ethylenediamine

I. Ježo and I. Lužák

Slovak Academy of Sciences, Bratislava

Abstract: cf. CA 61, 2039a. The aminolysis of sucrose was carried out with an aq. soln. of ethylenediamine. The following compds. were isolated and identified: 2-methyl-2-imidazoline, 2-ethyl-2-imidazoline, 2-hydroxy-6,7-dihydro-8-azaquinolizine, piperazino[a]-3-hydroxy-8-azaquinolizidine and piperazino[a]-3-hydroxy 8-aza-Δ8,9(9,10)-dehydroquinolizidine. A reaction mechanism is proposed.

Full paper in Portable Document Format: 183a186.pdf (in Slovak)

Chemical Papers 18 (3) 186–198 (1964)