ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
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Acidic catalysis of the ionization of bis(1-chloroethyl) sulfide

J. Beneš and K. Smolka

Vojenska Akad. Anton. Zapotockeho, Brno

 

Abstract: In substitution reactions of bis(2-chloroethyl) sulfide the dissocn. of the C.sbd.Cl bond is catalyzed by H ions. The kinetic measurements were carried out with sodium thiosulfate; 12 equations, 2 tables and 1 illustration were shown. It was detd. that the slowest part of the total change is the cleavage of the bond between C and Cl in the transient pos. charged intermediate.

Full paper in Portable Document Format: 184a259.pdf (in Czech)

 

Chemical Papers 18 (4) 259–265 (1964)

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