ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7

Published monthly
 

Cross-linking of saturated polymers on grafting

M. Lazár and R. Rado

Slovak Academy of Sciences, Bratislava

 

Abstract: A theoretical analysis of the cross-linking of satd. polymers on grafting with some monomers is given. The cross-linking during grafting is detd. by the part recombination plays with respect to the final termination, by a relation of the rate of the termination to the sum of rate of transfer reactions, and by a relation of the rate of reaction of initiator radicals with a basic polymer to the rate of their addn. onto the monomer. The effect of the character of the decompn. of polymer hydroperoxides plays with respect to the cross-linked structure of the grafted polymer is discussed. Also, differences were pointed out in the exptl. detn. of the degree of cross-linking upon immediate linking of linear chains and upon cross-linking during grafting.

Full paper in Portable Document Format: 156a435.pdf (in Slovak)

 

Chemical Papers 15 (6) 435–440 (1961)

Tuesday, September 27, 2022

IMPACT FACTOR 2021
2.146
SCImago Journal Rank 2021
0.365
SEARCH
Advanced
VOLUMES
European Symposium on Analytical Spectrometry ESAS 2022
© 2022 Chemical Papers