ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
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Phase diagrams of some systems important in electrolytic production of magnesium. I. Two-component systems MgCl2-NaCl, CaCl2-NaCl, and MgCl2-CaCl2

K. Matiašovský

Slovak Academy of Sciences, Bratislava

 

Abstract: By thermal (TA) and differential (DA) thermal analyses the exact compns. and temps. of characteristic points in phase diagrams of 2-component systems MgCl2-NaCl, CaCl2-NaCl, and MgCl2-CaCl2 were detd. CaCl2-NaCl is a simple eutectic system and in MgCl2-CaCl2 system in the area of high CaCl2 concn., solid solns. of MgCl2 in CaCl2 are formed. The exact limitation of satn. cannot be detd. by TA and DA because of the liquefaction.

Full paper in Portable Document Format: 132a69.pdf (in Slovak)

 

Chemical Papers 13 (2) 69–77 (1959)

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