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Inner complex salts of beryllium with organic acids of the type Be4O(RCO2)6

Ľ. Krasnec, J. Krätsmár-Šmogrovič, and A. Pivoda

Komenský University, Bratislava

 

Abstract: The formation of inner complex salts of Be with 1- or 2-naphthoic acid is described. The reaction in benzene medium of freshly pptd. Be(OH)2 with 1- and 2-naphthoic acids yields [Be4O(1-C10H7COO)6], m. 246.5°, and [Be4O(2-C10H7-COO)6], m. 335.5-6.5°, resp. The equation is 4Be(OH)2 + 6RCO2H = Be4O(RCO2) + 7H2O, where RCO2H is 1- or 2-naphthoic acid.

Full paper in Portable Document Format: 1110a575.pdf (in Slovak)

 

Chemical Papers 11 (10) 575–578 (1957)

Monday, June 24, 2024

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