ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

The hydrolysis and condensation of the esters of orthotitanic acid

E. Bišťan and I. Gömöry

Forschungsinstitut für Kabel und Isolierstoffe in Bratislava

Abstract: Expts. on the hydrolysis and condensation of Ti(OR₄) (R = Bu, heptyl, cetyl, PhCH₂, Ph, and m-MeC₆H₄) in the mol. ratios H₂O-Ti = 0.5:1, 1:1, and 2:1 are described. By comparing the esters it was found that the quantity of H₂O not used up in the reaction is dependent on the type of ester, and from the values so derived their resistance to hydrolysis can be judged. In the aliphatic esters the resistance to hydrolysis increases with the length of the chain of the alc. while in the aromatic esters it is considerably greater.

Full paper in Portable Document Format: 102a91.pdf (in Slovak)

Chemical Papers 10 (2) 91–95 (1956)