ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7
Preparation of 6-acetyl-1,2-isopropylidene-α-D-glucofuranose
J. Staněk and I. Hauzar
Charles University, Prague.
Abstract: By reaction of BzCl and of p-MeC6H4SO2Cl with the borate of 1,2-isopropylidene-α-D-glucofuranose (I) in a moisture-free medium, the 6-Bz, decomp. 196°, and the 6-p-tosyl, decomp. 116°, derivs., resp., of I are formed. I borate with Ac2O forms the borate, decomp. 120°, of 6-acetyl-1,2-isopropylidene-α-D-glucofuranose, which by boiling with MeOH forms 6-acetyl-1,2-isopropylidene-α-D-glucofuranose, decomp. 147°, and H3BO3.
Full paper in Portable Document Format: 86a337.pdf (in Czech)
Chemical Papers 8 (6) 337–341 (1954)