ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Osmometric study of aniline

B. Stehlík

Tech. Univ., Bratislava

Abstract: By the rush-membrane method mol. compds. of 2 mols. of aniline (I) with 1 mol. of MeOH, butanol, Et₂O, or acetone are indicated. The N atom of I is connected with the O atom of the other compd. by the H₂O mol. In mixts. of I with HCl, the anomalous (C₆H₅NH₂)₂.HCl was ascertained. Its rush no. x = 4 indicates that by the co.ovrddot.ordination of I to H ion the polarity of amine hydrogens is increased and that at the same time the H ion loses the ability to co.ovrddot.ordinate alcs.

Full paper in Portable Document Format: 31a1.pdf (in Slovak)

Chemical Papers 3 (1) 1–5 (1949)