ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Landfill leachate treatment using the sequencing batch biofilm reactor method integrated with the electro-Fenton process

Dao-Bin Zhang, Xiao-Gang Wu, Yi-Si Wang, and Hui Zhang

Department of Environmental Engineering, Hubei Biomass-Resource Chemistry and Environmental Biotechnology Key Laboratory, Wuhan University, Wuhan, 430079, China

E-mail: eeng@whu.edu.cn

Abstract: A study was conducted on the treatment of landfill leachate by combining the sequencing batch biofilm reactor (SBBR) method with the electro-Fenton method. The reduction of chemical oxygen demand (COD), biological oxygen demand (BOD₅), and ammonia nitrogen (NH₄⁺-N) from the leachate by the SBBR method was investigated. For the electro-Fenton experiment, the changes in COD and total organic carbon (TOC) with the increase in H₂O₂ dosage and electrolysis time under optimal conditions were also analysed. The results showed that the average efficiencies of reduction of COD, BOD₅, and NH₄⁺-N achieved using the SBBR method were 21.6 %, 54.7 %, and 56.1 %, respectively. The bio-effluent was degraded by the subsequent electro-Fenton process, which was rapid over the first 30 min then subsequently slowed. After 60 min of the electro-Fenton treatment, the efficiencies of reduction of TOC, COD, and BOD₅ were 40.5 %, 71.6 %, and 61.0 %, respectively. There is a good correlation between the absorbance of leachate at 254 nm (UV₂₅₄) and COD or TOC during the electro-Fenton treatment.

Keywords: leachate – SBBR – electro-Fenton – molecular mass distribution – UV254

Full paper is available at www.springerlink.com.

DOI: 10.2478/s11696-013-0504-8

Chemical Papers 68 (6) 782–787 (2014)