ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Effect of fuel content on formation of zinc aluminate nano and micro-particles synthesised by high rate sol–gel autoignition of glycine-nitrates

Shiva Salem

Faculty of Chemical Engineering, Urmia University of Technology, Band Street, 57166-17165, Urmia, Iran

E-mail: s.salem@che.uut.ac.ir

Abstract: The autoignition technique using glycine as fuel and related nitrate salts as an oxidiser is able to produce zinc aluminate spinel. The precursors were synthesised with lean and rich fuel at pH of 7.0 and the materials so obtained were calcined at various temperatures ranging from 600-1200°C. The autoignition process of precursors was studied by the simultaneous thermo-gravimetric and differential thermal analyses to determine the ignition mechanism. The calcined powders were characterised by X-ray diffraction, Brunauer-Emmett-Teller technique and transmission electron microscopy. The product contains nano-sized particles with an average size of approximately 20 nm. The XRD patterns showed the formation of ZnO in the powder obtained by the fuel-rich precursor and calcined at 600°C which disappears at 800°C due to solid-state reaction and proper crystallisation after heat treatment. The results presented here can be useful in manufacturing nano and micro-sized ZnAl₂O₄ on an industrial scale using the combustion technique.

Keywords: nano particle – zinc aluminate – autoignition – glycine – calcination

Full paper is available at www.springerlink.com.

DOI: 10.1515/chempap-2015-0205

Chemical Papers 70 (3) 356–364 (2016)