ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Dimethyl carbonate synthesis over solid base catalysts derived from Ca–Al layered double hydroxides

Yunhui Liao, Feng Li, Xin Dai, Ning Zhao, and Fukui Xiao

Chinese Academy of Sciences, Taiyuan, People’s Republic of China

E-mail: lifeng2729@sxicc.ac.cn

Abstract: The Ca–Al oxide catalysts are prepared via thermal decomposition of Ca–Al layered double hydroxide precursors and characterized by XRD, TG, SEM, BET, CO₂-TPD, Hammett indicators, XPS and ICP techniques. The obtained catalysts are then tested for transesterification of methanol with propylene carbonate (PC), highest dimethyl carbonate (DMC) yield of 59.9% has been reached with methanol: PC molar ratio of 12, catalysts weight of 2 wt% total reactants, and reaction time of 2 h. Research results show that though the transesterification occurs over various basic sites, the strong basic site has a leading role on transesterification, which is consistent with the activity results. The catalysts can be recycled and the reason for the decrease in catalytic activity is further discussed in detail. The catalytic performance of Ca-Al solid base catalysts derived from Ca-Al layered double hydroxides for dimethyl carbonate production under heterogeneous conditions.

Keywords: Transesterification ; Propylene carbonate ; Dimethyl carbonate ; Ca–Al layered double hydroxides ; Ca–Al solid base catalysts 

Full paper is available at www.springerlink.com.

DOI: 10.1007/s11696-018-0408-8

Chemical Papers 72 (8) 1963–1971 (2018)