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CuO nanoparticles-catalyzed a novel method to the synthesis of symmetrical diselenides from aryl halides: selenoamide as an organic Se-donor reagent

Mohammad Soleiman-Beigi, Issa Yavari, and Fatemeh Sadeghizadeh

Ilam University, Ilam, Iran

 

E-mail: SoleimanBeigi@yahoo.com

Abstract: A new method is reported for the synthesis of symmetrical diaryldiselenides from aryl halides using selenoamide as an organic Se-donor reagent in the presence of copper (II) oxide nanoparticles. CuO nanoparticles were found to be an efficient and inexpensive catalyst for ligand-free C-Se bond formation with a series of symmetrical diaryldiselenides obtained in good to excellent yield.

Keywords: Diaryldiselenides ; Selenoamide ; Se-donor ; Copper (II) oxide ; Nanoparticles 

Full paper is available at www.springerlink.com.

DOI: 10.1007/s11696-018-0450-6

 

Chemical Papers 72 (9) 2239–2246 (2018)

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