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ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7
Published monthly
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Parametric optimization and modeling of continuous electrocoagulation process for the removal of fluoride: Response surface methodology and machine learning approach
Pankaj D. Indurkar, Savan K. Raj, and Vaibhav Kulshrestha
Membrane Science and Separation Technology Division, CSIR-Central Salt and Marine Chemicals Research Institute, Bhavnagar, India
E-mail: pankajdi@csmcri.res.in
Received: 4 August 2023 Accepted: 21 November 2023
Abstract: The main objective of this study was to assess the continuous electrocoagulation process effectiveness for removing fluoride from potable water. The effect of different parameters like applied potential, electrode spacing, and feed flow rate was optimized for the continuous removal of fluoride from potable water. Response surface methodology (RSM) was used to examine the impact on essential operational factors such as voltage, concentration, and pH for fluoride removal as a response. The results demonstrate that all the parameters had a significant effect on removal efficiency. The quadratic model accurately predicted the optimal parameters for maximal fluoride removal efficiency with the association of desirability 1.0, which was discovered to be voltage 2.38 V, feed concentration 5.52 mg/L, and pH 6.45. According to the analysis of variance, R2 of the proposed quadratic model is higher (0.9877). Moreover, the difference between the predicted R2 of 0.9258 and the adjusted R2 of 0.9767 was less than 0.2. The model adequacy was also studied based on residual plot, perturbation plot, and box-cox plot. The RSM was best modeling techniques use to predict data than the multilayer perceptron and linear regression due to high accuracy. Finally, the generated flocs were characterized by scanning electron microscopy, energy-dispersive X-ray, X-ray diffraction, and Fourier transform infrared spectroscopy instrumental techniques. The outcomes demonstrate that a newly designed continuous electrocoagulation process is a promising alternative for the removal of fluoride from potable water.
Keywords: Electrocoagulation; Fluoride; Modeling; Central composite design; Machine learning
Full paper is available at www.springerlink.com.
DOI: 10.1007/s11696-023-03229-w
Chemical Papers 78 (4) 2193–2212 (2024)
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