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ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7
Published monthly
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Reaction of cadmium(II) and zinc(II) ions with hydrogen sulfide in molten lithium and potassium chlorides
J. Malá and I. Sláma
Institute of Inorganic Cliemistry, Czechoslovak Academy of Sciences,
250 68 Řež near Prague
Abstract: Basing on the study of the kinetics of the reaction of hydrogen sulfide with
cadmium(II) and zinc(II) ions dissolved in the molten lithium chloride—potassium
chloride eutectic mixture at 400 — 500°C, the kinetic equation of
the above reaction was derived and experimentally verified. The most
probable reaction mechanism was proposed and the corresponding relation
for the rate of reaction was compared with the kinetic equation. The rate
of the investigated reactions was compared with that of the reaction of
hydrogen sulfide with pure molten lithium and potassium chloride mixture
and with this mixture containing dissolved lead(II) ions. The range of validity
of the derived relations is discussed.
Full paper in Portable Document Format: 286a733.pdf
Chemical Papers 28 (6) 733–742 (1974)
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