ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Surfactant-assisted synthesis of polyaniline nanofibres without shaking and stirring: effect of conditions on morphology and conductivity

Ali Olad, Fahimeh Ilghami, and Rahimeh Nosrati

Polymer Composite Research Laboratory, Department of Applied Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, Iran

E-mail: a.olad@yahoo.com

Abstract: Polyaniline (PANI) nanofibres were synthesised by the chemical oxidative polymerisation method using ammonium peroxydisulphate (APS) as an oxidant/initiator. In this work, a surfactant-assisted method without shaking and stirring was used for the synthesis of PANI nanofibres. The effect was investigated of various parameters such as monomer/oxidant ratio, polymerisation temperature, and the presence of surfactant (Triton X-100 as a non-ionic surfactant) on the morphology and electrical conductivity of nanofibres. The morphology of PANI nanofibres was characterised by scanning electron microscopy and transmission electron microscopy. The results demonstrate that the morphology of PANI nanofibres was significantly influenced by the aniline/APS mole ratio, polymerisation temperature and presence of the surfactant during synthesis. The results showed that more regular and consistent nanofibres were obtained using a monomer/oxidant ratio of 4 at ambient temperature of polymerisation. PANI nanofibres with diameters in the range of 10–100 nm and length up to several μm were obtained. PANI nanofibres were also characterised using FTIR and UV-VIS absorption spectroscopy. The electrochemical behaviour of PANI nanofibres was studied by cyclic voltammetry. It was found that the electrical conductivity of PANI nanofibres increased with the increasing monomer/oxidant ratio and decreasing polymerisation temperature, respectively.

Keywords: conducting polymers – polymer synthesis and characterisation – morphology – nanofibres

Full paper is available at www.springerlink.com.

DOI: 10.2478/s11696-012-0197-4

Chemical Papers 66 (8) 757–764 (2012)