ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Thermodynamically Consistent Composition Dependence of Quantities of Mixture in Multicomponent Systems

J. Strečko and I. Proks

Institute of Inorganic Chemistry, Slovak Academy of Sciences, SK-842 36 Bratislava

Abstract: The paper gives an evidence that isobaric-isothermal composition dependence of molar quantities of mixing in binary systems ∆_mixE=x(1-x)φ(x), introduced by Guggenheim, which is the only one consistent with the method of intercepts equation, can be generalized to an analogous relation valid for k-component systems (k>2) and all quantities of mixture.

Full paper in Portable Document Format: 486a367.pdf

Chemical Papers 48 (6) 367–370 (1994)