ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7

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Preparation of aldoses by ozonolysis of sodium-salts of 1-deoxy-1-nitroalditols

E. Lattová, M. Petrušová, and L. Petruš

Institute of Chemistry, Slovak Academy of Sciences, CS-84238 Bratislava

 

Abstract: Treatment of aqueous solution of sodium salts of 1-deoxy-1-nitroalditols with ozone at room temperature results in high yields of the corresponding aldoses. By application of this new method L-glucose, L-mannose, D-glycero-D-gulo-heptose, D-glycero-D-ido-heptose, and D-glycero-L-manno-heptose have been prepared. Utilization of ozone in this conversion was 20 to 55 %.

Full paper in Portable Document Format: 456a823.pdf

 

Chemical Papers 45 (6) 823–827 (1991)

Wednesday, November 27, 2024

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