ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Magnetochemical investigation of trichloro(aliphatic alcohol)titanium(III) complexes

M. Kohútová

Institute of Inorganic Chemistry, Slovak Academy of Sciences, 809 34 Bratislava

Abstract: The magnetic properties of trichloro(aliph. alc.)titanium(III) complexes at 77-300 K were studied. The complexes TiCl₃.4CH₃OH, TiCl₃.4C₂H₅OH, TiCl₃.3n-C₃H₇OH, TiCl₃.4i-C₃H₇OH, TiCl₃.3n-C₄H₉OH, and TiCl₃.3i-C₄H₉OH have effective magnetic moments at room temp. of 1.79-1.86 μB. The results are interpreted by using Figgis' method (1961). On the basis of the data and interpretation of diffuse reflectance spectra the structure of magnetically noninteracting structural units, which are considered to have tetragonally distorted octahedral symmetry, is proposed for these complexes.

Full paper in Portable Document Format: 332a187.pdf

Chemical Papers 33 (2) 187–196 (1979)