ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Magnetochemical behavior of polymeric chloroalkoxotitanium(III) compounds

M. Kohútová and M. Zikmund

Institute of Inorganic Chemistry, Slovak Academy ofSciencest 809 34 Bratislava

Abstract: The magnetic properties of chloroalkoxotitanium(III) compds. formed in the course of thermal decompn. of chloro(aliph. alc.)titanium(III) complexes (C_nH_2n+1OH; n = 1-4) were studied. These products were of nonstoichiometric compn. and showed anomalously lowered values of effective magnetic moments even at room temp. The exptl. obtained values of μ_eff at 77-300 K are interpreted by using the Ising model of linear antiferromagnetism, and , on the basis of this, a neighboring Ti(III) atoms is proposed.

Full paper in Portable Document Format: 332a197.pdf

Chemical Papers 33 (2) 197–205 (1979)