ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Thermogravimetric and spectral study of some chloro(nitrile)titanium(III) complexes

M. Zikmund, A. Valent, and M. Kohútová

Institute of Inorganic Chemistry, Slovak Academy of Sciences, 809 34 Bratislava

Abstract: Titanium(III) chloride reacts with nitrile ligands to form the complexes TiCI₃ 3RCN (R = CH₃, CH₂ = CH, C₆H₅, C₆H₅CH₂), and TiCl₃ 4CH₃CN. The thermal decomposition reactions of these complexes were studied by thermogravimetric method in nitrogen atmosphere and under reduced pressure. The intermediates were isolated and identified by chemical and physical methods.

Full paper in Portable Document Format: 332a217.pdf

Chemical Papers 33 (2) 217–228 (1979)