ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Copper(II) complexes with organic ligands. XVII. Salicylato- and cresotatocopper(II) complexes with pyridine N-oxide and 2-methylpyridine N-oxide

M. Kohútová, J. Krätsmár-Šmogrovič, and O. Švajlenová

Institute of Inorganic Chemistry, Slovak Academy of Sciences, 809 34 Bratislava

Abstract:  Two modifications of salicylato-Cu(II) complex with 2-methylpyridine-N-oxide and o-, m-, and p-cresotato-Cu(II) complexes with pyridine-N-oxide and 2-methylpyridine-N-oxide were prepared. With the exception of Cn(p-cres)₂(pyox) (eres = cresotate anion, pyox = pyridine-N-oxide), all the isolated complexes have the composition Cu(R —COO)₂L₂. The assumed structure of the prepared complexes is discussed on the basis of the study of the temperature dependence of their magnetic properties and their electronic spectra in the solid state.

Full paper in Portable Document Format: 293a373.pdf

Chemical Papers 29 (3) 373–380 (1975)